A buoy is easy, they're comparatively big. It's not a field I or someone else needs to return to, GPS isn't needed for that.
Try finding a 1 cm radius nest hole of a rare bee that's been spotted in the 16 foot radius circle of ground the US system points to, when it's covered with mixed dense vegetation or woodland floor litter. That's when you realise how useless the US system is for such an application. Galileo will reduce the search area to under one tenth of the USA area, much more useful. The area ratio is about 10.3 to one in favour of Galileo.
That's just one example, there are many more natural world ones and no doubt there will be many more subjects with higher accuracy needs.
I notice you're are questioning elsewhere how a system can be any better than the present US system. I understand it initially comes down to the number of geolocation satellites accessed for each location measurement, 20 would derive a far more accurate location than 5 for example, due to error averaging and centre point selection. It's the old classic bell curve again, the more samples, the greater the peak point accuracy. Below is an extract about Galileo:
"Now, Europe has decided it can do better. After 17 years of development and billions spent, on Dec. 15, the European Union flipped the switch and turned on Galileo, its own satellite navigation system. Right now, it includes 18 live satellites, but by 2020 there will be 24—and when the system is at 100%, it should be accurate to within three feet, AFP reports. There will also be a sort of “professional” version of the system that, the European Space Agency says, will be precise to within centimeters. In large part this is thanks to the mind-boggling precision of the atomic clocks carried on their satellites, which are accurate to one second in 3 million years."
That 3 feet accuracy is for civilian use, Galileo is primarily a civilian system, that intentional on the EU's part to avoid coupling with other's military systems and the security threat that could introduce.
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