this research seems promising. It may lead to much longer life for our e-bike batteries.
quote:
A novel single-ion conducting polymer electrolyte (SIPE) based on ionic liquid (IL)-decorated PMMA nanoparticles dispersed in a propylene carbonate (PC) host is reported. This SIPE possesses a superior lithium-ion transference number (tLi+) of 0.96 with an enhanced ionic conductivity of 3.13 × 10−3 S cm−1 at room temperature and a wide electrochemical window up to ∼5.18 V. The enhanced ionic conductivity is ascribed to the unique brush-like structure of ionic liquid groups tethered to PMMA nanoparticles. Furthermore, the developed SIPE was found to be more efficient in suppressing lithium dendrite formation on a cycled lithium anode. As little as 11 wt% PMMA-IL-TFSI in a LiTFSI/PC host produces more than a ten-fold increase in the cell lifetime. On the other hand, this SIPE exhibits shear-thinning behavior which can be advantageously utilized in electrolyte processing. In addition, galvanostatic cycling measurements in Li/Li4Ti5O12 half cells using this SIPE exhibit excellent rate performance. Even at an extremely high charging rate of 875 mA g−1 (5C), the capacity is still around 100 mA h g−1, that is over 57% of the theoretical capacity (175 mA h g−1). These attributes enable the developed SIPE to be a promising candidate for high-performance lithium batteries.
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