Hi Ronnie,
I know of a few suppliers of 32h front motor hubs, but rear ones seem to be a rarity - apart from an occasional supplier that will do custom drilling, I've only seen them available a couple of times from German e-bike suppliers. They weren't a familiar make or design and at the low power end of the market.
I've built plenty of wheels with 36h hubs into 32h rims, but I'm not too keen to try it with a moderately powerful e-wheel for obvious reasons!
Assuming you mean you want to rebuild the orignal wheel with a motor, the only thing you'd keep is the rim. Why not keep the wheel complete in case you want to reuse it?
Rims are not too expensive and you'd have the certainty of a new, unstressed rim with the motor of your choice.
Alan (Catsnapper)