5s1p 8000mah is about the highest you can get in 5s form they are rated 30c 240a capable but generally for longevity a 1/4 of the actual rating is better used for good life which is still 60a continuous. Though as £60 odd each for a kids bike a similar priced 10s 10ah lion will do the job, I can though see the advantage of using the 5S for RC stuff if the pack size fits.
With my Graphene 10s 8ah lipo's I get about 25mile range with 3.6v - 4.1v SOC per cell, the advantage with lipo for a lot of users is the price point compared to lion especially if you already have the chargers etc,etc.
Hobbyking use to be the go to place for high capacity packs and a favourite among ebike users due to the price but you do have to put up with their at times poor CS.