The pressing the break doesn't work on a Woosh because there's too much delay before the motor starts again. The gear-changing is hardly a problem. You'll soon figure out what to do. You'll soon learn to select the correct gear before starting a hill.
You can get even more speed if you turn the wheel-magnet round. The speed is then only limited by your gearing. You can get higher and lower gearing at the same time if you swap the back-wheel for a cassette one, then you'll have a top assistance speed of over 30 mph.
When you release the speed limit, it doesn't change the power in any way. It's still a 250w motor, so your unassisted (throttle only) speed will be about 19 to 20 mph; however, the motor will speed you up down hills or with the wind behind you, or if you can pedal hard enough, it'll always be adding something to your pedalling. The higher the gear you're in, the lower the torque you get, so if you choose too high a gear, the bike won't have enough torque, so you slow down, just like in a car.