The Do's and Dont's of paralleling batteries.
1 They
MUST be the same specified voltage.
2 They
MUST be charged seperately (i,e disconnected from each other). This can be with their own individual chargers or use the same charger consecutively.
3 You must always check that the state of charge (soc) voltage is equal BEFORE you connect them together -
EVERY TIME.
A voltage difference of 0.1v is tolerable though not ideal. If one battery is higher than the other I generally finish the lower battery with the charger from the higher battery, this usually brings them in.
4 The connection lead, or Y lead, should have clearly marked connectors (mine are red and black) to avoid wrong polarity connection as this would be catastrophic. I use single pole Anderson Power plugs physically slotted together - difficult to reverse connect but not impossible so pay attention. Some sort of 2 pole irreversible plug and socket would be better, perhaps others can advise.
5 Ideally the batteries are the same capacity though not essentially, however I think they should be close as possible for best operation. Mine are both nominally rated at 14Ah. As they contain different cells and are of different ages, there will be a difference. I couldn't say how this would play out when running to near empty as that has never happened - that's why I've got two batteries
.
6 If carried in a pannier or rucksack, the second battery must be physically protected. I take mine out of the pannier for every charge so that it gets a visual inspection. Pay attention to the charge and discharge leads.
I am a sparky by training and am aware that even low voltage batteries can be very 'lively' if mistreated. Just because 36v doesn't give you a discernable shock don't disrespect it. The current flow of wrongly connected D.C. can be immense and extremely damaging.
I was taught a mnemonic as a lad. IT'S THE VOLTS THAT JOLTS, IT'S THE MILS THAT KILLS.
In other words a body can withstand a high voltage shock BUT if there is a current flow of only 30mA (especially across the heart) this is the killer. This illustrates that it's current that does the damage. In practice, you are never going to feel a shock from a 24 or 36v battery, but the current from it can burn you and anything around, badly.
So be aware, stay alert and you'll stay alive.