To what tolerance, +/-1mV, +/-10mV, +/-100mV??
A 36v battery pack ican be thought of as being made up of groups of 10*18650 cells in series. These cells have a typical fully charged voltage of 4.20V +/-50mV each, so 10 of these in series would give 42.0V +/-500mV
ie a nominal voltage of somewhere between 41.5V and 42.5V in total.
There's nothing in the 18650's chemistry to say that its fully charged voltage should be exactly 42.000V. Also, the "fully charged" voltage will depend on many things including the cell design & chemistry, the charging current and charging methodology, the temperature during charging, the way the charger maintains the fully charged state, the age of the cell, has the cell been used with high current loads, with low current loads, at high operating temperature, at low operating temperature, has it been stored at a low temperature, was it fully charged when stored at a low temperature etc etc etc.
Welcome to the world of physics and engineering vs "I would bet that a fully accurate meter would read 42 volts!"
This link may give you a clue as to some of the complexities involved:
Review simple guidelines for charging Lithium-based batteries and prolong battery life such as; a portable device should be turned off while charging and more.
batteryuniversity.com